EPA Method 23

ALS - Columbia offers EPA Method 23 testing at these laboratories:

Houston, Texas Laboratory

Method information displayed is provided for informational purposes only. No warranty (express or implied) is made as to the website accuracy, completeness, or applicability (such as the age of a method and whether or not it applies to your project). Please contact us for assistance.

View Actual EPA Method 23 (PDF File)


EPA Method 23:
Determination of Polychlorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans from Municipal Waste Combustors

Summary:
A sample is withdrawn isokinetically from the gas stream and collected in the sample probe, on a glass fiber filter, and on a packed column of adsorbent material. The sample cannot be separated into a particle and vapor fraction. The PCDD's and PCDF's are extracted from the sample, separated by high resolution gas chromatography (HRGC), and measured by high resolution mass spectrometry (HRMS).

Scope:
This method is applicable to the determination of emissions of polychlorinated dibenzo-p-dioxins (PCDD's) and polychlorinated dibenzofurans (PCDF's) from stationary sources.

Citation:
The official copy of this method is available at 40 Code of Federal Regulations (CFR) 60, Appendix A. The CFR can be accessed on-line at http://www.gpoaccess.gov/cfr/index.html

Interferences:
None Specified

QC Requirements:
(A) Internal Standard Percent Recoveries. A group of nine carbon-labeled PCDDs and PCDFs representing the tetra- through octachlorinated homologues, is added to every sample prior to extraction. The role of the internal standards is to quantify the native PCDD's and PCDF's present in the sample as well as to determine the overall method efficiency.(B) Surrogate Standard Recoveries/Sampling Train Collection Efficiency Check. Five surrogate compounds are added to the resin in the adsorbent sampling cartridge before the sample is collected. The surrogate recoveries are measured relative to the internal standards and are a measure of the collection efficiency.(C) Toluene QA Rinse: The adsorbent must be checked for residual toluene prior to use.(D)Audit Sample Requirement: When the method is used to analyze samples to demonstrate compliance with a source emission regulation, an audit sample must be analyzed, subject to availability. Analyze an audit sample with each set of compliance samples. The audit sample contains tetra through octa isomers of PCDD and PCDF. Concurrently analyze the audit sample and a set of compliance samples in the same manner to evaluate the technique of the analyst and the standards preparation. The same analyst, analytical reagents, and analytical system shall be used both for the compliance samples and the EPA audit sample.

Media:
AIR

Subcategory:
Organic

Concentration:
Varies with Analyte

Precision:
-

Detection:
The limits presented represent the lowest calibration point for a standard. Method 23 also provides an equation for calculating the mininum detectable limit.

Revision Number:
1995


At least 46 analytes can be tested by ALS - Columbia using EPA Method 23. Please contact us for all available analytes which can be tested by EPA Method 23.

Analyte	CAS Number
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin (HpCDD)	35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin-C13	109719-83-7
1,2,3,4,6,7,8-Heptachlorodibenzofuran (HpCDF)	67562-39-4
1,2,3,4,6,7,8-Heptachlorodibenzofuran-C13	109719-84-8
1,2,3,4,7,8,9-Heptachlorodibenzofuran (HpCDF)	55673-89-7
1,2,3,4,7,8,9-Heptachlorodibenzofuran-C13	109719-94-0
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin (HxCDD)	39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin-C13	109719-80-4
1,2,3,4,7,8-Hexachlorodibenzofuran (HxCDF)	70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran-C13	114423-98-2
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin (HxCDD)	57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin-C13	109719-81-5
1,2,3,6,7,8-Hexachlorodibenzofuran (HxCDF)	57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran-C13	116843-03-9
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin (HxCDD)	19408-74-3
1,2,3,7,8,9-Hexachlorodibenzofuran (HxCDF)	72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran-C13	116843-04-0
1,2,3,7,8-Pentachlorodibenzo-p-dioxin (PeCDD)	40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-dioxin-C13	109719-79-1
1,2,3,7,8-Pentachlorodibenzofuran (PeCDF)	57117-41-6
1,2,3,7,8-Pentachlorodibenzofuran-C13	109719-77-9
2,3,4,6,7,8-Hexachlorodibenzofuran (HxCDF)	60851-34-5
2,3,4,7,8-Pentachlorodibenzofuran (PeCDF)	57117-31-4
2,3,4,7,8-Pentachlorodibenzofuran-C13	116843-02-8
2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD)	1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin-C13	76523-40-5
2,3,7,8-Tetrachlorodibenzo-p-dioxin-Cl37	85508-50-5
2,3,7,8-Tetrachlorodibenzofuran (TCDF)	51207-31-9
2,3,7,8-Tetrachlorodibenzofuran-C13	89059-46-1
Heptachlorodibenzo-p-dioxins (HpCDD), Total	37871-00-4
Heptachlorodibenzofurans (HpCDF), Total	38998-75-3
Hexachlorodibenzo-p-dioxins (HxCDD), Total	34465-46-8
Hexachlorodibenzofurans (HxCDF), Total	55684-94-1
Octachlorodibenzo-p-dioxin (OCDD)	3268-87-9
Octachlorodibenzo-p-dioxin-C13	114423-97-1
Octachlorodibenzofuran (OCDF)	39001-02-0
Pentachlorodibenzo-p-dioxin (PeCDD), Total	36088-22-9
Pentachlorodibenzofurans (PeCDF), Total	30402-15-4
Tetrachlorodibenzo-p-dioxins (TCDD), Total	41903-57-5
Tetrachlorodibenzofurans (TCDF), Total	30402-14-3
Total TCDD TEQ - 2005 WHO (ND = 0)	CASID30360D
Total TCDD TEQ - 2005 WHO (ND = 0.5 * EDL)	CASID30360E
Total TCDD TEQ - EPA (ND = 0)	CASID30360
Total TCDD TEQ - EPA (ND = 0.5 * EDL)	CASID30360A
Total TCDD TEQ - WHO (ND = 0)	CASID30360B
Total TCDD TEQ - WHO (ND = 0.5 * EDL)	CASID30360C

	Examples:	8260 TO-15
	Examples:	Dioxin Mercury

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