EPA Method 26A


ALS - Columbia offers EPA Method 26A testing at these laboratories:

Rochester Rochester, New York Laboratory

ALS - Columbia offers the following EPA Method 26 variations:

EPA Method 26 testing is available at the Kelso Laboratory.

Method information displayed is provided for informational purposes only. No warranty (express or implied) is made as to the website accuracy, completeness, or applicability (such as the age of a method and whether or not it applies to your project). Please contact us for assistance. Analytical testing dots

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EPA Method 26A:
DETERMINATION OF HYDROGEN HALIDE AND HALOGEN EMISSIONS FROM STATIONARY SOURCES ISOKINETIC METHOD

Summary:
Gaseous and particulate pollutants are withdrawn isokinetically from the source and collected in an optional cyclone, on a filter, and in absorbing solutions. The cyclone collects any liquid droplets and is not necessary if the source emissions do not contain them; however, it is preferable to include the cyclone in the sampling train to protect the filter from any liquid present. The filter collects particulate matter including halide salts but is not routinely recovered or analyzed. Acidic and alkaline absorbing solutions collect the gaseous hydrogen halides and halogens, respectively. Following sampling of emissions containing liquid droplets, any halides/halogens dissolved in the liquid in the cyclone and on the filter are vaporized to gas and collected in the impingers by pulling conditioned ambient air through the sampling train. The hydrogen halides are solubilized in the acidic solution and form chloride (Cl-), bromide (Br-), and fluoride (F-) ions. The halogens have a very low solubility in the acidic solution and pass through to the alkaline solution where they are hydrolyzed to form a proton (H+), the halide ion, and the hypohalous acid (HClO or HBrO). Sodium thiosulfate is added to the alkaline solution to assure reaction with the hypohalous acid to form a second halide ion such that 2 halide ions are formed for each molecule of halogen gas. The halide ions in the separate solutions are measured by ion chromatography (IC). If desired, the particulate matter recovered from the filter and the probe is analyzed following the procedures in Method 5.

Scope:
This method is applicable for determining emissions of hydrogen halides (HX) [HCl, HBr, and HF] and halogens (X2) [Cl2 and Br2] from stationary sources when specified by the applicable subpart. This method collects the emission sample isokinetically and is therefore particularly suited for sampling at sources, such as those controlled by wet scrubbers, emitting acid particulate matter (e.g., hydrogen halides dissolved in water droplets).

Test Description:
Vapor Tightness of G

Date Issued:
1/21/1994

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At least 3 analytes can be tested by ALS - Columbia using EPA Method 26A. Please contact us for all available analytes which can be tested by EPA Method 26A.

AnalyteCAS Number
Bromide24959-67-9
Chloride16887-00-6
Fluoride16984-48-8





Examples:  8260
TO-15

Examples:  Dioxin
Mercury
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